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Pure Chemistry · TOPIC 12

Maintaining Air Quality

SEAB syllabus topic 12: what dry air is made of, which pollutants harm it and how they are dealt with, the ozone layer, the carbon cycle and global warming, with the reasons, the common mistakes and an exam check for every outcome.

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Maintaining Air Quality
8 outcomes · air, pollutants, the ozone layer and the carbon cycle ✦
Air and pollutants

Dry air is approximately 78% nitrogen and 21% oxygen, and the pollutants carbon monoxide, nitrogen oxides and sulfur dioxide come from incomplete combustion, lightning, engines, volcanoes and fossil fuels.

Solutions and effects

A catalytic converter and flue gas desulfurisation with calcium carbonate remove pollutants, and sulfur dioxide and nitrogen dioxide would otherwise form acid rain that corrodes buildings.

Ozone, carbon and climate

The ozone layer absorbs harmful ultraviolet radiation, the carbon cycle regulates carbon dioxide, and carbon dioxide and methane are greenhouse gases and may contribute to global warming.

SUPPORTS K324-12(a)

Composition of dry air

K324-12(a)6092-12(a)

describe the volume composition of gases present in dry air as being approximately 78% nitrogen, 21% oxygen and the remainder being noble gases (with argon as the main constituent) and carbon dioxide

Core idea

Dry air is approximately 78% nitrogen and 21% oxygen by volume, and the remainder is noble gases, with argon as the main constituent, and carbon dioxide.

Dry air
Dry air: air from which the water vapour has been removed, which is the air that the composition figures describe
Volume composition
Volume composition: the share of the total volume of a gas mixture that each gas makes up, usually given as a percentage
Nitrogen, N2
Nitrogen, N2: the main gas in dry air, at approximately 78% by volume
Oxygen, O2
Oxygen, O2: the second most abundant gas in dry air, at approximately 21% by volume, and the gas that living things use in respiration and that fuels use in burning
Noble gases
Noble gases: the unreactive gases of Group 18 that make up most of the remainder of dry air, with argon, Ar, as the main constituent
Carbon dioxide, CO2
Carbon dioxide, CO2: a gas present in dry air in a very small share by volume, which plants use in photosynthesis
Mixture
Mixture: two or more substances that are not chemically joined, so each gas in air keeps its own properties supports K324-12(a)

Gases in dry air

GasPictureFormulaShare of the volume of dry airNote
NitrogenNitrogen molecule N2N2Nitrogen makes up approximately 78% of the volume of dry air.Nitrogen is the main gas in dry air.
OxygenOxygen molecule O2O2Oxygen makes up approximately 21% of the volume of dry air.Oxygen is the second most abundant gas in dry air.
ArgonArgon atomArArgon is part of the remainder of dry air, and it is the main constituent of the noble gases.Argon is the third most abundant gas in dry air.
Other noble gasesOther noble gas atomsNe, He, Kr, XeThe other noble gases are part of the remainder of dry air.The other noble gases are present in much smaller shares than argon.
Carbon dioxideCarbon dioxide molecule CO2CO2Carbon dioxide is part of the remainder of dry air.Carbon dioxide is present in a very small share by volume.
Composition of dry air. A horizontal bar represents the whole volume of dry air. Nitrogen fills approximately 78 per cent of the bar and oxygen approximately 21 per cent, drawn to scale. The remainder is a very thin sliver at the right-hand end. A zoomed inset, not to scale, shows what the remainder contains: mostly argon, a smaller share of the other noble gases and a very small share of carbon dioxide.
Figure 1. Dry air is approximately 78% nitrogen and 21% oxygen by volume, and the remainder is noble gases, with argon as the main constituent, and carbon dioxide.

Water vapour is not counted in the composition of dry air, because the amount of water vapour in the air changes from place to place. supports K324-12(a)

Showing that air contains oxygen

Removing the oxygen from air

2Cu(s) + O2(g) → 2CuO(s)Heating copper in a fixed volume of air removes the oxygen as black copper(II) oxide, so the volume of gas decreases and the gas left behind is mainly nitrogen.

Exam tip

The SEAB glossary says “State implies a concise answer with little or no supporting argument, e.g. a numerical answer that can be obtained ‘by inspection’”, so when asked to state the composition of dry air, give approximately 78% nitrogen and 21% oxygen without extra explanation.

Fractional distillation of air

Fractional distillation of air. Dry air enters a cooling unit and leaves as liquid air, which is fed into the middle of a tall fractionating column. Gas rises through trays in the column. Nitrogen, with the lowest boiling point, leaves first at the top, argon is drawn off from the middle, and oxygen, with the highest boiling point of the three, is collected at the bottom. Numbers 1, 2 and 3 show the order of boiling off.
Figure 2. In fractional distillation of liquid air, nitrogen leaves first because it has the lowest boiling point, then argon, and oxygen leaves last because it has the highest boiling point of the three.
💡 SGSK Shortcut
Gases in dry air by volume

Never Overlook Air's Components

In decreasing order of volume, dry air contains nitrogen, oxygen, argon and carbon dioxide.Key: N is nitrogen, O is oxygen, A is argon (the main noble gas, so write noble gases, with argon the main one, when asked for the remainder) and C is carbon dioxide.
Bottom line

Dry air is approximately 78% nitrogen and 21% oxygen, and the remainder is mainly argon and the other noble gases together with a little carbon dioxide.

Depth: why and how

  • Why is the composition given for dry air? The amount of water vapour in air changes from place to place and from day to day, so the composition is quoted for air with the water vapour removed.
  • How can you show that oxygen is only part of air? Heating copper in a fixed volume of air removes the oxygen, so the volume of gas decreases, and the gas that is left is mainly nitrogen.
  • Why do the noble gases not take part when a fuel burns in air? Noble gases are unreactive, so they stay unchanged.
  • Why does carbon dioxide stay a small part of the air even though many processes release it? Plants and other producers remove carbon dioxide by photosynthesis, as the carbon cycle section explains.
  • Cross-link to Experimental Chemistry: air is a mixture, so its gases keep their own properties and can be separated by a physical method such as fractional distillation.

Common mistakes

❌ What students write

Air is approximately 78% oxygen and 21% nitrogen.

✅ Mark-scheme wording

Dry air is approximately 78% nitrogen and 21% oxygen, so nitrogen is the main gas and not oxygen.

❌ What students write

Air is a compound of nitrogen and oxygen.

✅ Mark-scheme wording

Air is a mixture of gases, so the gases in it are not chemically joined.

❌ What students write

The remainder of dry air is mostly carbon dioxide.

✅ Mark-scheme wording

The remainder of dry air is mostly noble gases, with argon as the main constituent, and carbon dioxide is a very small part.

❌ What students write

Argon is the second most common gas in dry air.

✅ Mark-scheme wording

Oxygen is the second most common gas in dry air, and argon, the main noble gas, comes third.

Exam check

Q1Which gas is the main constituent of dry air?

  • Aoxygen
  • Bargon
  • Ccarbon dioxide
  • Dnitrogen
Show answer

MCQ answer key D (nitrogen): dry air is approximately 78% nitrogen, which is more than any other gas.

Q2Which noble gas is the main constituent of the remainder of dry air after nitrogen and oxygen?

  • Ahelium
  • Bneon
  • Cxenon
  • Dargon
Show answer

MCQ answer key D (argon): K324 names argon as the main constituent of the noble gases in dry air, and the other noble gases are present in much smaller shares.

Q3Which statement about dry air is correct?

  • AIt is a mixture of gases.
  • BIt is a compound of nitrogen and oxygen.
  • CIt contains more oxygen than nitrogen.
  • DIt is mostly argon.
Show answer

MCQ answer key A (It is a mixture of gases.): the gases in air are not chemically joined, and nitrogen, at approximately 78%, is the main gas.

StructuredDry air is a mixture of gases.

  1. State the approximate percentage by volume of nitrogen and of oxygen in dry air. [2]
  2. Name the main noble gas in dry air. [1]
  3. Name one gas in dry air that is neither nitrogen, oxygen nor a noble gas. [1]
  4. Suggest why the composition of air is given for dry air. [2]

Total: 6 marks

Show mark scheme
(a) 2 marks
  • Mark scheme: nitrogen is approximately 78%
  • Mark scheme: oxygen is approximately 21%
(b) 1 mark
  • Mark scheme: argon
(c) 1 mark
  • Mark scheme: carbon dioxide
(d) 2 marks
  • Mark scheme: the amount of water vapour in air changes
  • Mark scheme: so the percentages of the other gases would not be fixed
SUPPORTS K324-12(b)

Common atmospheric pollutants

K324-12(b)6092-12(b)

name some common atmospheric pollutants, e.g. carbon monoxide; methane; nitrogen oxides (NO and NO2); ozone; sulfur dioxide; unburned hydrocarbons

Core idea

Common atmospheric pollutants include carbon monoxide, methane, nitrogen oxides (NO and NO2), ozone, sulfur dioxide and unburned hydrocarbons.

Atmospheric pollutant
Atmospheric pollutant: a substance in the air that harms the health of living things or damages the environment
Carbon monoxide, CO
Carbon monoxide, CO: a colourless and odourless poisonous gas
Methane, CH4
Methane, CH4: the simplest hydrocarbon, which is a pollutant because it is a greenhouse gas
Nitrogen oxides, NO and NO2
Nitrogen oxides, NO and NO2: oxides of nitrogen, named nitrogen monoxide and nitrogen dioxide, which can form acid rain
Ozone, O3
Ozone, O3: a form of oxygen with three atoms in each molecule, which is a pollutant when it is near the ground
Sulfur dioxide, SO2
Sulfur dioxide, SO2: a colourless gas with a sharp smell that forms acid rain
Unburned hydrocarbons
Unburned hydrocarbons: fuel molecules, made of carbon and hydrogen only, that leave an engine or a furnace without being burned

Pollutants, sources, effects and remedies

PollutantPictureMain sourceHarm it doesRemedy
Carbon monoxide, COCarbon monoxide molecule COCarbon monoxide comes from the incomplete combustion of carbon-containing substances.Carbon monoxide is toxic.A catalytic converter changes carbon monoxide into carbon dioxide.
Methane, CH4Methane molecule CH4Methane comes from the decay of organic matter without oxygen and from livestock.Methane is a greenhouse gas that may contribute to global warming.Not required for K324 12(d); methane is dealt with as a greenhouse gas in 12(h).
Nitrogen oxides, NO and NO2Nitrogen oxides NO and NO2Nitrogen oxides come from lightning activity and internal combustion engines.Nitrogen dioxide takes part in the formation of acid rain.A catalytic converter reduces nitrogen oxides to nitrogen.
Ozone, O3Ozone molecule O3Ozone near the ground forms from nitrogen oxides and unburned hydrocarbons in sunlight, which is taught in schools but is not a K324 outcome.Ozone near the ground harms the lungs.Less ozone forms when fewer nitrogen oxides and unburned hydrocarbons are released.
Sulfur dioxide, SO2Sulfur dioxide molecule SO2Sulfur dioxide comes from volcanoes and the combustion of fossil fuels.Sulfur dioxide takes part in the formation of acid rain and harms breathing.Calcium carbonate removes sulfur dioxide from flue gas.
Unburned hydrocarbonsA hydrocarbon moleculeUnburned hydrocarbons are fuel that leaves an engine without being fully burned.Unburned hydrocarbons help to form ozone near the ground.A catalytic converter oxidises unburned hydrocarbons to carbon dioxide and water.

SEAB writes nitrogen oxides as NO and NO2, so be ready to give either the name or the formula. supports K324-12(b)

Exam tip

The SEAB glossary says “List requires a number of points, generally each of one word, with no elaboration. Where a given number of points is specified, this should not be exceeded”, so if a question asks you to list two pollutants, write exactly two names.

💡 SGSK Shortcut
The six pollutants in order

Cat Munches Noodles On Sunny Umbrellas

The six common atmospheric pollutants, in alphabetical order, are carbon monoxide, then methane, then nitrogen oxides, then ozone, then sulfur dioxide and last unburned hydrocarbons.Key: C is carbon monoxide, M is methane, N is nitrogen oxides, O is ozone, S is sulfur dioxide and U is unburned hydrocarbons.
Bottom line

Learn the six example pollutants as carbon monoxide, methane, nitrogen oxides, ozone, then sulfur dioxide and unburned hydrocarbons, and link each one to a source, a harm and a remedy.

Depth: why and how

  • Why is ozone both a pollutant and a protector? Ozone near the ground is breathed in and harms the lungs, but ozone high in the atmosphere absorbs harmful ultraviolet radiation.
  • Why are unburned hydrocarbons classed as pollutants? They take part with nitrogen oxides in the formation of ozone near the ground in sunlight.
  • Why is methane named as a pollutant when it is also a fuel? Methane is a greenhouse gas, so it traps heat when it escapes into the air even though it is useful as natural gas.
  • Which of the named pollutants are oxides? Carbon monoxide, nitrogen oxides and sulfur dioxide are oxides, but ozone is a form of oxygen and not an oxide.
  • Is carbon dioxide one of the pollutants named in K324 outcome 12(b)? No, K324 treats carbon dioxide as a greenhouse gas in outcome 12(h) and not as one of the pollutants in this list.
  • Cross-link to Organic Chemistry: a hydrocarbon is a compound made of carbon and hydrogen only, and methane is the simplest hydrocarbon.

Common mistakes

❌ What students write

Carbon dioxide is a poisonous pollutant like carbon monoxide.

✅ Mark-scheme wording

Carbon monoxide is the pollutant that K324 singles out as toxic, because it reduces the oxygen the blood carries, whereas carbon dioxide is not poisonous in this way and is treated as a greenhouse gas.

❌ What students write

Ozone is harmful wherever it is found.

✅ Mark-scheme wording

Ozone near the ground is a pollutant, but ozone in the ozone layer protects living things from ultraviolet radiation.

❌ What students write

Sulfur dioxide and nitrogen oxides are the same pollutant.

✅ Mark-scheme wording

Sulfur dioxide and nitrogen oxides are different pollutants with different formulae and sources, although both take part in acid rain.

❌ What students write

Unburned hydrocarbons form when a fuel burns completely.

✅ Mark-scheme wording

Unburned hydrocarbons are fuel molecules that escape without burning, and complete combustion forms carbon dioxide and water.

Exam check

Q1Which of these is an atmospheric pollutant?

  • Anitrogen
  • Bargon
  • Coxygen
  • Dsulfur dioxide
Show answer

MCQ answer key D (sulfur dioxide): sulfur dioxide is one of the pollutants named in K324, whereas nitrogen, argon and oxygen are normal constituents of dry air.

Q2Which pair of formulae represents the nitrogen oxides named in K324?

  • ACO and CO2
  • BN2 and O2
  • CNO and NO2
  • DSO2 and O3
Show answer

MCQ answer key C (NO and NO2): the nitrogen oxides are nitrogen monoxide, NO, and nitrogen dioxide, NO2.

Q3Which gas is a pollutant near the ground but absorbs ultraviolet radiation high in the atmosphere?

  • Aozone
  • Bmethane
  • Ccarbon monoxide
  • Dsulfur dioxide
Show answer

MCQ answer key A (ozone): ozone is harmful to the lungs near the ground, but the ozone layer absorbs harmful ultraviolet radiation.

StructuredThe air in a busy city contains several pollutants.

  1. Give the formulae of the two nitrogen oxides named in the syllabus. [2]
  2. State what is meant by unburned hydrocarbons. [1]
  3. Name the gas that is a pollutant near the ground but protects living things in the ozone layer. [1]
  4. Name two other pollutants from the six that K324 gives as examples. [2]

Total: 6 marks

Show mark scheme
(a) 2 marks
  • Mark scheme: NO
  • Mark scheme: NO2
(b) 1 mark
  • Mark scheme: fuel molecules, made of carbon and hydrogen only, that escape without being burned
(c) 1 mark
  • Mark scheme: ozone
(d) 2 marks
  • Mark scheme: any two from: carbon monoxide; methane; sulfur dioxide; unburned hydrocarbons (1 mark for each)
  • Mark scheme: accept any other correct atmospheric pollutant not already named in the question
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  • Sources of the pollutants
  • Solutions to pollution problems
  • Effects of the pollutants
  • The ozone layer and CFCs
  • The carbon cycle
  • Greenhouse gases and global warming

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Notes version 1.0 · Last updated 2 Oct 2026 · Chapter 12 of 13

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Chapter 12: Maintaining Air Quality

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